Synthesis and characterisation of a bridging nitrido complex of titanium

被引：17

作者：

Carmalt, CJ

Mileham, JD

White, AJP

Williams, DJ

机构：

[1] UCL, Christopher Ingold Labs, Dept Chem, London WC1H 0AJ, England

[2] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England

来源：

NEW JOURNAL OF CHEMISTRY | 2000年 / 24卷 / 12期

关键词：

D O I：

10.1039/b008211m

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Titanium tetrachloride reacts with hexamethyldisilazane in the presence of 3,5-dimethylpyridine (L) to form a bridging nitrido species, [{Ti(2)Cl(5)(L)(5)}(mu -N)], the structure of which has been established by X-ray crystallography.

引用

页码：929 / 930

页数：2

共 18 条

[1] Ammonolysis of mono(pentamethylcyclopentadienyl) titanium(IV) derivatives [J].

Abarca, A ;

Gómez-Sal, P ;

Martín, A ;

Mena, M ;

Poblet, JM ;

Yélamos, C .

INORGANIC CHEMISTRY, 2000, 39 (04) :642-651

[2] Bis(trimethylsilyl)ammonium salts obtained by reaction of hexamethyldisilazane with TiCl4, ZrCl4, or SnCl4 [J].

Bettenhausen, R ;

Milius, W ;

Schnick, W .

CHEMISTRY-A EUROPEAN JOURNAL, 1997, 3 (08) :1337-1341

[3] Titanium(IV)azido and imido complexes as potential precursors to titanium nitride [J].

Carmalt, CJ ;

Whaley, SR ;

Lall, PS ;

Cowley, AH ;

Jones, RA ;

McBurnett, BG ;

Ekerdt, JG .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (04) :553-557

[4] Monomeric titanium(IV) azides as a new route to titanium nitride [J].

Carmalt, CJ ;

Cowley, AH ;

Culp, RD ;

Jones, RA ;

Sun, YM ;

Fitts, B ;

Whaley, S ;

Roesky, HW .

INORGANIC CHEMISTRY, 1997, 36 (14) :3108-3112

[5] NITRIDO COMPLEXES OF TRANSITION-METALS [J].

DEHNICKE, K ;

STRAHLE, J .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1992, 31 (08) :955-978

[6] A novel bis(azatitanatrane) with a T-shaped nitrido bridging ligand: Synthesis and structure of {[N(CH2CH2N-i-Pr)(3)Ti](2)(mu(3)-N)Na(THF)} [J].

Duan, ZB ;

Verkade, JG .

INORGANIC CHEMISTRY, 1996, 35 (18) :5325-5327

[7] SYNTHESIS OF THIN-FILMS BY ATMOSPHERIC-PRESSURE CHEMICAL VAPOR-DEPOSITION USING AMIDO AND IMIDO TITANIUM(IV) COMPOUNDS AS PRECURSORS [J].

FIX, RM ;

GORDON, RG ;

HOFFMAN, DM .

CHEMISTRY OF MATERIALS, 1990, 2 (03) :235-241

[8] Syntheses and structures of di- and trinuclear heterometallic complexes with nitrido bridges between rhenium and titanium [J].

Gauch, E ;

Hoppe, H ;

Strähle, J .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2000, 593 :175-179

[9]

GOMEZSAL P, 1995, CHEM COMMUN, P2185

[10] CHEMICAL-VAPOR-DEPOSITION OF NITRIDE THIN-FILMS [J].

HOFFMAN, DM .

POLYHEDRON, 1994, 13 (08) :1169-1179

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