Photochemistry and photophysics of coordination compounds: Rhenium

被引：216

作者：

Kirgan, Robert A. ^{[2
]}

Sullivan, B. Patrick ^{[1
]}

Rillema, D. Paul ^{[2
]}

机构：

[1] Univ Wyoming, Dept Chem, Laramie, WY 82071 USA

[2] Wichita State Univ, Dept Chem, Wichita, KS 67260 USA

来源：

PHOTOCHEMISTRY AND PHOTOPHYSICS OF COORDINATION COMPOUNDS II | 2007年 / 281卷

关键词：

photochemistry; photophysics; rhenium; luminescence; excited-state; PHOTOINDUCED ELECTRON-TRANSFER; LIGAND SUBSTITUTION-REACTIONS; TRICARBONYL CORE COMPLEXES; METAL CHARGE-TRANSFER; C-CL BOND; EXCITED-STATES; MOLECULAR RECTANGLES; CRYSTAL-STRUCTURE; LUMINESCENCE SPECTRA; CONJUGATED POLYMERS;

D O I：

10.1007/128_2007_143

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This review describes recent advances in the photochemistry of complexes of the element rhenium. It covers not only fundamental chemistry but the recent applications of these complexes to supramolecular chemistry, carbon dioxide reduction, bioinorganic chemistry, sensors, and light-emitting devices.

引用

收藏

页码：45 / 100

页数：56

相关论文

共 128 条

[51]

KIRGAN R, UNPUB OBSERVATIONS

[52] Syntheses and reactions of the complexes (η5-C5Me5)Re(CO)2(C6Cl5-nHn)Cl (n=2,3):: Compounds derived from initial C-Cl activation [J].

Klahn, AH ;

Carreño, M ;

Godoy, F ;

Oelckers, B ;

Pizarro, A ;

Toro, A ;

Reyes, A .

JOURNAL OF COORDINATION CHEMISTRY, 2001, 54 (3-4) :379-388

[53] Intermolecular C-Cl activation reaction of (π5-C5R5)Re(CO)3 (R = H, Me) with pentachlorobenzene:: X-ray structure of cis- and trans-(η5-C5Me5)Re(CO)2(2,3,4,5-C6HCl4)Cl and its conversion to (η6-C5Me4CH2)Re(CO)2(2,3,4,5-C6HCl4) [J].

Klahn, AH ;

Toro, A ;

Oelckers, B ;

Buono-Core, GE ;

Manriquez, V ;

Wittke, O .

ORGANOMETALLICS, 2000, 19 (13) :2580-2584

[54] Synthesis, characterization and photochromic studies of spirooxazine-containing 2,2'-bipyridine ligands and their rhenium(I) tricarbonyl complexes [J].

Ko, CC ;

Wu, LX ;

Wong, KMC ;

Zhu, NY ;

Yam, VWW .

CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (03) :766-776

[55] Triplet MLCT photosensitization of the ring-closing reaction of diarylethenes by design and synthesis of a photochromic rhenium(I) complex of a diarylethene-containing 1,10-phenanthroline ligand [J].

Ko, Chi-Chiu ;

Kwok, Wai-Ming ;

Yam, Vivian Wing-Wah ;

Phillips, David Lee .

CHEMISTRY-A EUROPEAN JOURNAL, 2006, 12 (22) :5840-5848

[56] Mechanism of the photochemical ligand substitution reactions of fac-[Re(bPY)(CO)3(PR3)]+ complexes and the properties of their triplet ligand-field excited states [J].

Koike, K ;

Okoshi, N ;

Hori, H ;

Takeuchi, K ;

Ishitani, O ;

Tsubaki, H ;

Clark, IP ;

George, MW ;

Johnson, FPA ;

Turner, JJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (38) :11448-11455

[57] Key process of the photocatalytic reduction of CO2 using [Re(4,4′-X2-bipyridine)(CO)3PR3]+ (X = CH3, H, CF3;: PR3 = phosphorus ligands):: Dark reaction of the one-electron-reduced complexes with CO2 [J].

Koike, K ;

Hori, H ;

Ishizuka, M ;

Westwell, JR ;

Takeuchi, K ;

Ibusuki, T ;

Enjouji, K ;

Konno, H ;

Sakamoto, K ;

Ishitani, O .

ORGANOMETALLICS, 1997, 16 (26) :5724-5729

[58] New synthetic routes to biscarbonylbipyridinerhenium(I) complexes cis,trans-[Re(X2bpy)(CO)2(PR3)(Y)]n+ (X2bpy=4,4′-X2-2,2′-bipyridine) via photochemical ligand substitution reactions, and their photophysical and electrochemical properties [J].

Koike, K ;

Tanabe, J ;

Toyama, S ;

Tsubaki, H ;

Sakamoto, K ;

Westwell, JR ;

Johnson, FPA ;

Hori, H ;

Saitoh, H ;

Ishitani, O .

INORGANIC CHEMISTRY, 2000, 39 (13) :2777-2783

[59] Photoreactivity of the triphenylphosphine adduct of methyl(trioxo)rhenium(VII) induced by ligand-to-metal charge transfer excitation [J].

Kunkely, H ;

Vogler, A .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2000, 606 (02) :207-209

[60] Photolysis of CH3Re(O2)2O induced by ligand-to-metal charge transfer and by peroxide intraligand excitation [J].

Kunkely, H ;

Vogler, A .

INORGANIC CHEMISTRY COMMUNICATIONS, 2005, 8 (05) :467-470

← 1 2 3 4 5 6 7 8 9 10 →