Effect of fluoride coating on in vitro dynamic degradation of Mg-Zn alloy

被引:15
作者
Chen, Ying [1 ]
Song, Yang [1 ]
Zhang, Shaoxiang [1 ]
Li, Jianan [1 ]
Wang, Hongju [1 ]
Zhao, Changli [1 ]
Zhang, Xiaonong [1 ]
机构
[1] Shanghai Jiao Tong Univ, Sch Mat Sci & Engn, State Key Lab Met Matrix Composites, Shanghai 200240, Peoples R China
关键词
Mg-Zn; Degradation; Fluoride; Coating; Electrochemical; Dynamic; CORONARY-ARTERIES; MAGNESIUM ALLOYS; CORROSION; BEHAVIOR; BIOCOMPATIBILITY; STENTS;
D O I
10.1016/j.matlet.2011.05.108
中图分类号
T [工业技术];
学科分类号
120111 [工业工程];
摘要
A compact and flat fluoride coating with some pores was prepared on a Mg-Zn alloy in order to control its degradation behavior. The electrochemical tests demonstrated that the real impedance (Z(re)) of the fluoride-coated Mg-Zn was approximately 10 times as large as that of the untreated alloy. The free corrosion potential (E(corr)), compared to that of the uncoated Mg-Zn alloy, increased 646 mV for the coated metal. The free corrosion current (I(corr)) of the Mg-Zn specimen with the fluoride film was about one tenth of that of the uncoated one. The in vitro dynamic degradation tests showed that the average weight loss of the fluoride-coated Mg-Zn was lower than that of the untreated alloy in the initial 4 h of the tests, indicating the film could function as a barrier coating on Mg-Zn matrix. However, the coating cracked and peeled severely after 4 h dynamic tests, which implied that the fluoride coating could not endure the sustaining washing of the modified simulated body fluid. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:2568 / 2571
页数:4
相关论文
共 16 条
[1]
Dynamic degradation behavior of MgZn alloy in circulating m-SBF [J].
Chen, Ying ;
Zhang, Shaoxiang ;
Li, Jianan ;
Song, Yang ;
Zhao, Changli ;
Zhang, Xiaonong .
MATERIALS LETTERS, 2010, 64 (18) :1996-1999
[2]
Characterization and corrosion studies of fluoride conversion coating on degradable Mg implants [J].
Chiu, K. Y. ;
Wong, M. H. ;
Cheng, F. T. ;
Man, H. C. .
SURFACE & COATINGS TECHNOLOGY, 2007, 202 (03) :590-598
[3]
In-vivo measurements of wall shear stress in human coronary arteries [J].
Doriot, PA ;
Dorsaz, PA ;
Dorsaz, L ;
De Benedetti, E ;
Chatelain, P ;
Delafontaine, P .
CORONARY ARTERY DISEASE, 2000, 11 (06) :495-502
[4]
Development and biocompatibility of a novel corrodible fluoride-coated magnesium-calcium alloy with improved degradation kinetics and adequate mechanical properties for cardiovascular applications [J].
Drynda, Andreas ;
Hassel, Thomas ;
Hoehn, Rene ;
Perz, Angela ;
Bach, Friedrich-Wilhelm ;
Peuster, Matthias .
JOURNAL OF BIOMEDICAL MATERIALS RESEARCH PART A, 2010, 93A (02) :763-775
[5]
Temporary scaffolding of coronary arteries with bioabsorbable magnesium stents:: a prospective, non-randomised multicentre trial [J].
Erbel, Raimund ;
Di Mario, Carlo ;
Bartunek, Jozef ;
Bonnier, Johann ;
de Bruyne, Bernard ;
Eberli, Franz R. ;
Erne, Paul ;
Haude, Michael ;
Heublein, Bernd ;
Horrigan, Mark ;
Ilsley, Charles ;
Boese, Dirk ;
Koolen, Jacques ;
Luescher, Thomas F. ;
Weissman, Neil ;
Waksman, Ron .
LANCET, 2007, 369 (9576) :1869-1875
[6]
Influence of surface modification on the in vitro corrosion rate of magnesium alloy AZ31 [J].
Gray-Munro, Joy E. ;
Seguin, Christine ;
Strong, Michael .
JOURNAL OF BIOMEDICAL MATERIALS RESEARCH PART A, 2009, 91A (01) :221-230
[7]
In vitro corrosion and biocompatibility of binary magnesium alloys [J].
Gu, Xuenan ;
Zheng, Yufeng ;
Cheng, Yan ;
Zhong, Shengping ;
Xi, Tingfei .
BIOMATERIALS, 2009, 30 (04) :484-498
[8]
Early restenosis following biodegradable stent implantation in an aortopulmonary collateral of a patient with pulmonary atresia and hypoplastic pulmonary arteries [J].
McMahon, Colin J. ;
Oslizlok, Paul ;
Walsh, Kevin P. .
CATHETERIZATION AND CARDIOVASCULAR INTERVENTIONS, 2007, 69 (05) :735-738
[9]
Mechanism of chemical conversion coating film growth on magnesium and magnesium alloys [J].
Ono, S ;
Asami, K ;
Masuko, N .
MATERIALS TRANSACTIONS, 2001, 42 (07) :1225-1231
[10]
Preparation and assessment of revised simulated body fluids [J].
Oyane, A ;
Kim, HM ;
Furuya, T ;
Kokubo, T ;
Miyazaki, T ;
Nakamura, T .
JOURNAL OF BIOMEDICAL MATERIALS RESEARCH PART A, 2003, 65A (02) :188-195