Efficient and catalytic conversion of epoxides to 1,3-dioxolanes with TiO(TFA)2 or TiCl3(OTf)

被引:39
作者
Iranpoor, N [1 ]
Zeynizadeh, B [1 ]
机构
[1] Shiraz Univ, Coll Sci, Dept Chem, Shiraz 71454, Iran
来源
JOURNAL OF CHEMICAL RESEARCH-S | 1998年 / 08期
关键词
D O I
10.1039/a801283k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
TiO(TFA)(2) or TiCl3(OTf) catalyses the efficient reaction of epoxides with acetone to give the corresponding 1,3-dioxolanes in excellent yields. The reaction of chiral styrene oxide was found to be highly stereospecific.
引用
收藏
页码:466 / 467
页数:3
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