Synthetic methods for the preparation of 1,3-propanediol

被引:106
作者
Kraus, George A. [1 ,2 ]
机构
[1] Iowa State Univ, Dept Chem, Ames, IA 50011 USA
[2] Iowa State Univ, Inst Phys Res & Technol, Ames, IA 50011 USA
关键词
fermentation; hydroformylation; 1,3-propanediol; synthesis;
D O I
10.1002/clen.200800084
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The market for 1,3-propanediol (PDO) is currently over 100 million pounds per year and is growing rapidly. PDO is a component of industrial polyesters such as Dupont's Sorona (R) and CDP Natureworks (R) or Shell Chemical's Corterra (TM). Markets for the polyester include thermoplastics, textiles, carpets, and upholstery. This paper reviews the methods for the production of 1,3-propanediol by focusing on four feedstocks: glycerol, ethylene oxide, acrolein, and glucose.
引用
收藏
页码:648 / 651
页数:4
相关论文
共 27 条
[1]  
ALLEN KD, 2002, Patent No. 2002098887
[2]   Development of an improved continuous hydrogenation process for the production of 1,3-propanediol using titania supported ruthenium catalysts [J].
Besson, M ;
Gallezot, P ;
Pigamo, A ;
Reifsnyder, S .
APPLIED CATALYSIS A-GENERAL, 2003, 250 (01) :117-124
[3]  
BOCK R, 2002, FREIBERG FORSCHUNG A, V866, P125
[4]  
BOON WH, 2002, Patent No. 2002055759
[5]  
Emptage M, 2001, Process for the biological production of 1,3-propanediol, Patent No. [WO 2001012833, 2001012833]
[6]   Producing bio-based bulk chemicals using industrial biotechnology saves energy and combats climate change [J].
Hermann, B. G. ;
Blok, K. ;
Patel, M. K. .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2007, 41 (22) :7915-7921
[7]   The glycerin glut: Options for the value-added conversion of crude glycerol resulting from biodiesel production [J].
Johnson, Duane T. ;
Taconi, Katherine A. .
ENVIRONMENTAL PROGRESS, 2007, 26 (04) :338-348
[8]  
Kurian JV, 2005, NATURAL FIBERS, BIOPOLYMERS, AND BIOCOMPOSITES, P497
[9]   A new polymer platform for the future -: Sorona® from corn derived 1,3-propanediol [J].
Kurian, JV .
JOURNAL OF POLYMERS AND THE ENVIRONMENT, 2005, 13 (02) :159-167
[10]   Production of 1,3-propanediol by hydrogenolysis of glycerol catalyzed by Pt/WO3/ZrO2 [J].
Kurosaka, Tadahiro ;
Maruyama, Hideyuki ;
Naribayashi, Ikuya ;
Sasaki, Yoshiyuki .
CATALYSIS COMMUNICATIONS, 2008, 9 (06) :1360-1363