Controlling electroosmotic flow in microchannels with pH-responsive polyelectrolyte multilayers

被引:62
作者
Sui, ZJ
Schlenoff, JB [1 ]
机构
[1] Florida State Univ, Dept Chem & Biochem, Tallahassee, FL 32306 USA
[2] Florida State Univ, Ctr Mat Res & Technol, Tallahassee, FL 32306 USA
关键词
D O I
10.1021/la034682q
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A polyelectrolyte multilayer coating comprising acrylic acid or imidazole units afforded precise control over the rate and direction of electroosmotic flow within fused silica capillaries. Morphological changes accompanying the pH-induced switching of surface charge were minimized by diluting the pH-responsive polyelectrolyte with permanently charged polymer. Electroosmotic stability over many runs was demonstrated.
引用
收藏
页码:7829 / 7831
页数:3
相关论文
共 37 条
[1]   Plastic microfluidic devices modified with polyelectrolyte multilayers [J].
Barker, SLR ;
Tarlov, MJ ;
Canavan, H ;
Hickman, JJ ;
Locascio, LE .
ANALYTICAL CHEMISTRY, 2000, 72 (20) :4899-4903
[2]  
Bharadwaj R, 2002, ELECTROPHORESIS, V23, P2729, DOI 10.1002/1522-2683(200208)23:16<2729::AID-ELPS2729>3.0.CO
[3]  
2-I
[4]  
BRANHAM MM, 2000, J CAPILLARY ELECTROP, V6, P43
[5]   Influence of polyelectrolyte multilayer coatings on Forster resonance energy transfer between 6-carboxyfluorescein and rhodamine B-labeled particles in aqueous solution [J].
Caruso, F ;
Donath, E ;
Möhwald, H .
JOURNAL OF PHYSICAL CHEMISTRY B, 1998, 102 (11) :2011-2016
[6]   Layer-by-layer deposition: A tool for polymer surface modification [J].
Chen, W ;
McCarthy, TJ .
MACROMOLECULES, 1997, 30 (01) :78-86
[7]   Microchip-based capillary electrophoresis for immunoassays: Analysis of monoclonal antibodies and theophylline [J].
Chiem, N ;
Harrison, DJ .
ANALYTICAL CHEMISTRY, 1997, 69 (03) :373-378
[8]   Electroosmotically induced hydraulic pumping on microchips: Differential ion transport [J].
Culbertson, CT ;
Ramsey, RS ;
Ramsey, JM .
ANALYTICAL CHEMISTRY, 2000, 72 (10) :2285-2291
[9]   Fuzzy nanoassemblies: Toward layered polymeric multicomposites [J].
Decher, G .
SCIENCE, 1997, 277 (5330) :1232-1237
[10]  
Decher G., 2003, MULTILAYER THIN FILM