One-pot sequential and cascade formation of triazoles via palladium catalysed azide capture-1,3-dipolar cycloaddition

被引:43
作者
Gardiner, M
Grigg, R [1 ]
Kordes, M
Sridharan, V
Vicker, N
机构
[1] Univ Leeds, Sch Chem, Mol Innovat Divers & Automated Synth Ctr, Leeds LS2 9JT, W Yorkshire, England
[2] Rhone Poulenc Rorer, Dagenham Res Ctr, Dagenham RM10 7XS, England
基金
英国工程与自然科学研究理事会;
关键词
anion capture; azides; cascade; palladium; triazoles;
D O I
10.1016/S0040-4020(01)00737-2
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The development of cascade and sequential processes comprising the formation of allylic azides, from aryl/heteroaryl/vinyl halides, allene and sodium azide, by palladium catalysed anion capture, and cyclisation-anion capture, followed by 1,3-dipolar cycloaddition gives rise to a variety of new triazoles in good yield. (C) 2001 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:7729 / 7735
页数:7
相关论文
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