Improved syntheses of one-dimensional cyanide-bridged lanthanide-transition-metal arrays

被引：29

作者：

Du, B ^{[1
]}

Ding, ER ^{[1
]}

Meyers, EA ^{[1
]}

Shore, SG ^{[1
]}

机构：

[1] Ohio State Univ, Evans Lab Chem, Dept Chem, Columbus, OH 43210 USA

来源：

INORGANIC CHEMISTRY | 2001年 / 40卷 / 14期

关键词：

D O I：

10.1021/ic001340o

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complexes{(DMF)(10)Ho-2[Ni(CN)(4)](3)}infinity and {(DMF)(10-)Gd-2[Ni(CN)(4)](3)}infinity were prepared through an improved synthetic route. This method reduces the reaction time from 1-2 weeks to within 15-30 min. <Graphics>

引用

页码：3637 / 3638

页数：2

共 22 条

[1]

ASLANOV LA, 1971, ZH STRUKT KHIM, V12, P661

[2]

CERNAK J, 1988, REV INORG CHEM, V9, P259

[3] Direct evidence for O-H•••NC hydrogen bonding in a cyanide-bridged lanthanide-transition-metal complex (H2O)6(DMF)6Ho2[Ni(CN)4]3:: An eight-coordinated holmium center with a bicapped (square face) trigonal prismatic geometry [J].

Du, B ;

Meyers, EA ;

Shore, SG .

INORGANIC CHEMISTRY, 2000, 39 (20) :4639-4645

[4]

DU B, 2000, THESIS OHIO STATE U

[5]

DU B, UNPUB

[6]

Favas MC, 1978, PROGR INORGANIC CHEM, P179

[7] THERMODYNAMICS OF CHLORO COMPLEXATION OF LANTHANIDE(III) IONS IN N,N-DIMETHYLFORMAMIDE [J].

ISHIGURO, S ;

TAKAHASHI, R .

INORGANIC CHEMISTRY, 1991, 30 (08) :1854-1858

[8] Heterometallic one-dimensional arrays containing cyanide-bridged lanthanide(III) and transition metals [J].

Knoeppel, DW ;

Liu, JP ;

Meyers, EA ;

Shore, SG .

INORGANIC CHEMISTRY, 1998, 37 (19) :4828-4837

[9] Cyanide-bridged lanthanide-transition metal one-dimensional arrays {(DMF)(10)Yb-2[Ni(CN)(4)](3)}(infinity) and {(DMF)(10)Yb-2[Pt(CN)(4)](3)}(infinity) [J].

Knoeppel, DW ;

Shore, SG .

INORGANIC CHEMISTRY, 1996, 35 (07) :1747-&

[10] Unusual one-dimensional ladder structures containing divalent europium and the tetracyanometalates Ni(CN)(4)(2-) and Pt(CN)(4)(2-) [J].

Knoeppel, DW ;

Shore, SG .

INORGANIC CHEMISTRY, 1996, 35 (18) :5328-5334

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