The design and synthesis of biodegradable pyridinium ionic liquids

被引:75
作者
Harjani, Jitendra R. [1 ]
Singer, Robert D. [2 ]
Garcia, M. Teresa [3 ]
Scammells, Peter J. [1 ]
机构
[1] Monash Univ, Monash Inst Pharmaceut Sci, Parkville, Vic 3052, Australia
[2] St Marys Univ, Dept Chem, Halifax, NS B3H 3C3, Canada
[3] CSIC, IIQAB, Dept Surfactant Technol, Barcelona 08034, Spain
关键词
D O I
10.1039/b800534f
中图分类号
O6 [化学];
学科分类号
0703 [化学];
摘要
Ionic liquids with a pyridinium cation bearing an ester side chain moiety were prepared from either pyridine or nicotinic acid and their biodegradability was evaluated using the CO2 Headspace test (ISO 14593). ILs of this type showed exceptionally high levels of biodegradation under aerobic conditions and can be classified as 'readily biodegradable'.
引用
收藏
页码:436 / 438
页数:3
相关论文
共 22 条
[1]
Clean and green ... but are they mean? [J].
Adam, D .
NATURE, 2000, 407 (6807) :938-940
[2]
Anastas P.T., 1994, BENIGN DESIGN
[3]
Anastas PT., 1998, Principles of green chemistry
[4]
Designing small molecules for biodegradability [J].
Boethling, R. S. ;
Sommer, Elizabeth ;
DiFiore, David .
CHEMICAL REVIEWS, 2007, 107 (06) :2207-2227
[5]
Boethling RS, 1996, ACS SYM SER, V640, P156
[6]
BOETHLING RS, 1994, CATIONIC SURFACTANTS, V53, P95
[7]
Biodegradable ionic liquids: Selected synthetic applications [J].
Bouquillon, Sandrine ;
Courant, Thomas ;
Dean, Darrell ;
Gathergood, Nicholas ;
Morrissey, Saibh ;
Pegot, Bruce ;
Scammells, Peter J. ;
Singer, Robert D. .
AUSTRALIAN JOURNAL OF CHEMISTRY, 2007, 60 (11) :843-847
[8]
Biodegradability of imidazolium and pyridinium ionic liquids by an activated sludge microbial community [J].
Docherty, Kathryn M. ;
Dixon, JaNeille K. ;
Kulpa, Charles F., Jr. .
BIODEGRADATION, 2007, 18 (04) :481-493
[9]
Ionic liquid (molten salt) phase organometallic catalysis [J].
Dupont, J ;
de Souza, RF ;
Suarez, PAZ .
CHEMICAL REVIEWS, 2002, 102 (10) :3667-3691
[10]
Biodegradable ionic liquids: Part I. Concept, preliminary targets and evaluation [J].
Gathergood, N ;
Garcia, MT ;
Scammells, PJ .
GREEN CHEMISTRY, 2004, 6 (03) :166-175