Laser-induced gas-phase synthesis of dimeric C70 oxides

被引：16

作者：

Al-Jafari, MS

Barrow, MP

Taylor, R ^{[1
]}

Drewello, T

机构：

[1] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England

[2] Univ Sussex, CPES, Chem Lab, Brighton BN1 9QJ, E Sussex, England

来源：

INTERNATIONAL JOURNAL OF MASS SPECTROMETRY | 1999年 / 184卷 / 2-3期

关键词：

dimeric C-70 oxides; MALDI; time-of-flight mass spectrometry; fullerenes;

D O I：

10.1016/S1387-3806(99)00029-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

The greater lability of C-70 oxides towards oxygen release has been advanced recently to explain the failure to synthesise C140O from C70O; by contrast the analogous reactions with C-60 oxides result in the formation of fullerene oxide aggregates. The present report provides the first experimental evidence for the existence of oxides of the type (C-70)(2)O-n, resulting from gas-phase aggregation reactions when using matrix-assisted laser desorption/ionization to study synthetic, high performance liquid chromatography-purified C-70 oxides. (C) 1999 Elsevier Science B.V.

引用

页码：L1 / L4

页数：4

共 25 条

[1]

ALJAFARI MS, UNPUB

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