Unprecedented C-H bond oxidative addition of the imidazolium cation to Pt0:: a combined density functional analysis and experimental study

被引：111

作者：

McGuinness, DS

Cavell, KJ

Yates, BF

机构：

[1] Cardiff Univ, Dept Chem, Cardiff CF1 3TB, S Glam, Wales

[2] Univ Tasmania, Sch Chem, Hobart, Tas 7001, Australia

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 04期

关键词：

D O I：

10.1039/b009674l

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Density functional studies predict that oxidative addition of an imidazolium salt to a Pt-0 complex is an exothermic process, and consistent with this proposal, the reaction of the 1,3-dimethylimidazolium cation with Pt(PPh3)(4) yields a hydrido-Pt-II carbene complex.

引用

页码：355 / 356

页数：2

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