Synthesis and crystal structure of Cl3Ti[N(SiMe(2)Cl)(SiMe(2)NH(2))]

被引：12

作者：

Buheitel, R ^{[1
]}

Milius, W ^{[1
]}

Schnick, W ^{[1
]}

机构：

[1] UNIV BAYREUTH,ANORGAN CHEM LAB,D-95440 BAYREUTH,GERMANY

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1996年 / 51卷 / 08期

关键词：

silazanes; nitrido bridges; precursor; crystal structure;

D O I：

10.1515/znb-1996-0814

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Cl3Ti[N(SiMe(2)Cl)(SiMe(2)NH(2))] is yielded by reaction of TiCl4 with two molecules ClMe(2)SiNHSiMe(3). A single crystal structure determination (P2(1)/n, a = 747.12(2), b = 1294.1(3), c = 1496.7(3) pm, beta = 90.30(3)degrees, Z = 4) shows a planar four-membered ring Ti-N-Si-N as the central feature of the monomers formed by a weak coordinative bond of the NH2 group to the Ti atoms. The monomers are connected to give dimers via two Cl bridges linked to the Ti atoms.

引用

页码：1141 / 1144

页数：4

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