Enantioselective sulfoxidation mediated by vanadium-incorporated phytase:: a hydrolase acting as a peroxidase

被引：73

作者：

van de Velde, F ^{[1
]}

Könemann, L ^{[1
]}

van Rantwijk, F ^{[1
]}

Sheldon, RA ^{[1
]}

机构：

[1] Delft Univ Technol, Organ Chem & Catalysis Lab, NL-2628 BL Delft, Netherlands

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 17期

关键词：

D O I：

10.1039/a804702b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Phytase (E.C. 3.1.3.8), which in vivo mediates the hydrolysis of phosphate esters, catalyses the enantioselective oxidation of thioanisole with H2O2, both in the presence and absence of vanadate ion, affording the S-sulfoxide in up to 66% ee at 100% conversion.

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页码：1891 / 1892

页数：2

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