Novel 5 V spinel cathode Li2FeMn3O8 for lithium ion batteries

被引：100

作者：

Kawai, H

Nagata, M

Tabuchi, M

Tukamoto, H

West, AR

机构：

[1] Univ Aberdeen, Dept Chem, Aberdeen AB24 3UE, Scotland

[2] Japan Storage Battery Co Ltd, Corp R&D Ctr, Minami Ku, Kyoto 601, Japan

[3] Osaka Natl Res Inst, Ikeda, Osaka 563, Japan

来源：

CHEMISTRY OF MATERIALS | 1998年 / 10卷 / 11期

关键词：

D O I：

10.1021/cm9807182

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Li2FeMn3O8 acts as a reversible cathode material by (de)lithiation in cells: Li/LiPF6, propylene carbonate/LiXFeMn3O8. Initial discharge gives a plateau centered at 4.9 V attributable to the Fe-3+,Fe-4+ couple followed by a second plateau at 4.1 V with overall discharge capacity of 125 mA h g(-1).

引用

页码：3266 / +

页数：4

共 20 条

[1] A new three-volt spinel Li1+xMn1.5Ni0.5O4 for secondary lithium batteries
Amine, K
Tukamoto, H
Yasuda, H
Fujita, Y
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1996, 143 (05) : 1607 - 1613
[2] Synthesis of layered LiMnO2 as an electrode for rechargeable lithium batteries
Armstrong, AR
Bruce, PG
[J]. NATURE, 1996, 381 (6582) : 499 - 500
[3] Valence band of LiNixMn2-xO4 and its effects an the voltage profiles of LiNixMn2-xO4/Li electrochemical cells
Gao, Y
Myrtle, K
Zhang, MJ
Reimers, JN
Dahn, JR
[J]. PHYSICAL REVIEW B, 1996, 54 (23): : 16670 - 16675
[4] A novel cathode Li2CoMn3O8 for lithium ion batteries operating over 5 volts
Kawai, H
Nagata, M
Tukamoto, H
West, AR
[J]. JOURNAL OF MATERIALS CHEMISTRY, 1998, 8 (04) : 837 - 839
[5] Crystal chemistry and physical properties of complex lithium spinels Li2MM′3O8 (M = Mg, Co, Ni, Zn; M′ = Ti, Ge)
Kawai, H
Tabuchi, M
Nagata, M
Tukamoto, H
West, AR
[J]. JOURNAL OF MATERIALS CHEMISTRY, 1998, 8 (05) : 1273 - 1280
[6] KAWAI H, UNPUB
[7] A manganese oxyiodide cathode for rechargeable lithium batteries
Kim, JK
Manthiram, A
[J]. NATURE, 1997, 390 (6657) : 265 - 267
[8] LIXCOO2 "(OLESS-THANXLESS-THAN-OR-EQUAL-TO1) - A NEW CATHODE MATERIAL FOR BATTERIES OF HIGH-ENERGY DENSITY
MIZUSHIMA, K
JONES, PC
WISEMAN, PJ
GOODENOUGH, JB
[J]. MATERIALS RESEARCH BULLETIN, 1980, 15 (06) : 783 - 789
[9] Nagaura T., 1990, PROG BATT SOLAR CELL, V9, P209
[10] Novel low-temperature synthesis and characterization of LiNiVO4 for high-voltage Li ion batteries
Prabaharan, SRS
Michael, MS
Radhakrishna, S
Julien, C
[J]. JOURNAL OF MATERIALS CHEMISTRY, 1997, 7 (09) : 1791 - 1796

← 1 2 →