Novel phthalocyanine conductor containing two-dimensional Pc stacks, [PXX]2[Co(Pc)(CN)2] (PXX=peri-xanthenoxanthene, Co(Pc)(CN)2=dicyano(phthalocyaninato)cobalt(III))

被引：18

作者：

Asari, T

Naito, T

Inabe, T ^{[1
]}

Matsuda, M

Tajima, H

机构：

[1] Hokkaido Univ, Grad Sch Sci, Div Chem, Sapporo, Hokkaido 060810, Japan

[2] Univ Tokyo, Inst Solid State Phys, Kashiwa, Chiba 2778581, Japan

来源：

CHEMISTRY LETTERS | 2004年 / 33卷 / 02期

关键词：

D O I：

10.1246/cl.2004.128

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel phthalocyanine conductor containing 2-D pi-pi stacks of the partially oxidized Co(Pc)(CN)(2) units has been obtained by the electrochemical oxidation method with PXX. The crystal is highly conductive (> 10(3) S cm(-1)) at all the temperatures measured (5 K < T < 300 K). Though the metallic character becomes clearer compared with the single chain or ladder chain conductors, the 2-D sheet has been found to be still anisotropic.

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页码：128 / 129

页数：2

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