Self-assembly of copper(II) complexes with ladder, bi-rack, rack-ladder-rack and layer structures by the directional-bonding approach using a T-shaped ligand

被引：47

作者：

Wang, MS ^{[1
]}

Guo, GC ^{[1
]}

Fu, ML ^{[1
]}

Xu, L ^{[1
]}

Cai, Z ^{[1
]}

Huang, JS ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China

来源：

DALTON TRANSACTIONS | 2005年 / 17期

关键词：

D O I：

10.1039/b501782c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Six copper(II) complexes of trans-1,2,3-propenetricarboxylic acid (H3L) with novel ladder, bi-rack, rack-ladder-rack and layer structures were obtained by the combination of the diverse coordination symmetries and the Jahn-Teller effect of the Cu2+ ion and the T-shaped coordination mode of the L3- or HL2- ligand together with the introduction of an inert directing ligand. Solid-state photoluminescent analyses of the present compounds show that they display blue emissions.

引用

页码：2899 / 2907

页数：9

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