A crystalline microporous narrow-bandgap semiconductor

被引：14

作者：

Palmqvist, AEC ^{[1
]}

Iversen, BB

Zanghellini, E

Behm, M

Stucky, GD

机构：

[1] Chalmers Univ Technol, Dept Mat & Surface Chem, S-41296 Gothenburg, Sweden

[2] Chalmers Univ Technol, Competence Ctr Catalysis, S-41296 Gothenburg, Sweden

[3] Aarhus Univ, Dept Chem, DK-8000 Aarhus, Denmark

[4] Chalmers Univ Technol, Dept Phys & Engn Phys, S-41296 Gothenburg, Sweden

[5] Royal Inst Technol, Dept Chem Engn & Technol Appl Electrochem, S-10044 Stockholm, Sweden

[6] Univ Calif Santa Barbara, Dept Chem & Biochem, Dept Mat, Santa Barbara, CA 93106 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 06期

关键词：

D O I：

10.1002/anie.200351284

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A crystalline microporous semiconductor |(| K6(H 2O)6| [Sb12O18])3| [Te36] (denoted SBC-1) has been prepared, which consists of 24-ring tubular tellurium units that host 12-ring {Sb12O18} tubular units, which in turn act as hosts for K+ ions and H 2O molecules (see picture). An example of a second-order zeoate, it has a narrow bandgap of 0.25 eV and exhibits highly anisotropic electrical conductivity.

引用

页码：700 / 704

页数：5

共 19 条

[1] Real-space multiple-scattering calculation and interpretation of x-ray-absorption near-edge structure [J].

Ankudinov, AL ;

Ravel, B ;

Rehr, JJ ;

Conradson, SD .

PHYSICAL REVIEW B, 1998, 58 (12) :7565-7576

[2] PREPARATION AND CRYSTAL-STRUCTURE OF CSTE4 [J].

BOTTCHER, P ;

KRETSCHMANN, U .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1985, 523 (04) :145-152

[3] NATE3 - A COMPOUND WITH CUBAN-LIKE CLUSTERS TE-126- [J].

BOTTCHER, P ;

KELLER, R .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1986, 542 (11) :144-152

[4]

Hanko JA, 1998, ANGEW CHEM INT EDIT, V37, P342, DOI 10.1002/(SICI)1521-3773(19980216)37:3<342::AID-ANIE342>3.0.CO

[5]

2-P

[6] Ordered microporous and mesoporous materials with inorganic hosts: definitions of terms, formula notation, and systematic classification [J].

Liebau, F .

MICROPOROUS AND MESOPOROUS MATERIALS, 2003, 58 (01) :15-72

[7]

Liebau F., COMMUNICATION

[8] Nomenclature of structural and compositional characteristics of ordered microporous and mesoporous materials with inorganic hosts - (IUPAC recommendations 2001) [J].

McCusker, LB ;

Liebau, F ;

Engelhardt, G .

PURE AND APPLIED CHEMISTRY, 2001, 73 (02) :381-394

[9]

PALMQVIST AEC, 2001, 13 INT ZEOL C JUL 8

[10] Template synthesis of [Cr(en)(3)][Te-6]: A novel polytelluride with a framework structure, whose cavities are filled with a [Cr(en)(3)](3+) template [J].

Reisner, C ;

Tremel, W .

CHEMICAL COMMUNICATIONS, 1997, (04) :387-388

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