Preparation and electrochemical evaluation of poly (3-phenylthiophene) derivatives: potential materials for electrochemical capacitors

被引：94

作者：

Ferraris, JP ^{[1
]}

Eissa, MM ^{[1
]}

Brotherston, ID ^{[1
]}

Loveday, DC ^{[1
]}

Moxey, AA ^{[1
]}

机构：

[1] Univ Texas, Dept Chem, Richardson, TX 75083 USA

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1998年 / 459卷 / 01期

关键词：

cyclic voltammetry; polymerization efficiencies; charge densities;

D O I：

10.1016/S0022-0728(98)00318-0

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The preparation and electrochemical characterization using cyclic voltammetry, in situ quartz crystal microbalance measurements and ac impedance spectroscopy of five new monomers and polymers for electrochemical capacitors (ECC) are described. High polymerization efficiencies (similar to 70%) and charge densities (similar to 190 C g(-1)) were obtained for poly 3-(3,4-difluorophenylthiophene), MPFPT, and poly 3-(4-fluorophenylthiophene), PFPT. Excellent cycling stability (< 1% degradation over 100 cycles) was achieved for MPFPT in both p- and n-doping regimes. This enhanced cyclability is associated with polymers having rigid open structures. (C) 1998 Elsevier Science S.A. All rights reserved.

引用

页码：57 / 69

页数：13

共 54 条

[41] A STUDY OF THE ELECTROCHEMICAL PROPERTIES OF CONDUCTING POLYMERS FOR APPLICATION IN ELECTROCHEMICAL CAPACITORS [J].