Preparation, characterization, and crystal structure of [Ru2Cl(μ-O2CMe)(μ-PhNCHNPh)3]:: a way to tris(formamidinato)diruthenium(II,III) complexes

被引：38

作者：

Barral, MC

Herrero, S

Jiménez-Aparicio, R

Torres, MR

Urbanos, FA

机构：

[1] Univ Complutense Madrid, Fac Ciencias Quim, Dept Quim Inorgan, E-28040 Madrid, Spain

[2] Univ Complutense Madrid, Fac Ciencias Quim, Ctr Asistencia Invest Rayos X, E-28040 Madrid, Spain

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2004年 / 7卷 / 01期

关键词：

diruthenium compounds; metal-metal bonds; formamidinato complexes; ruthenium complexes; acetate complexes;

D O I：

10.1016/j.inoche.2003.09.016

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complex chloroacetatotris(N,N'-diphenylformamidinato)diruthenium(11,111), [Ru2Cl(mu-O2CMe)(mu-DPhF)(3)] (1), has been isolated in the reaction of [Ru2Cl(mu-O2CMe)(4)] with N,N'-diphenylformamidine (HDPhF) in thf. This complex is an intermediate in the total substitution process of acetate ligands in [Ru2Cl(mu-O2CMe)(4)] by formamidinate groups. The remaining acetate can be substituted by other ligands, allowing the use of compound 1 as starting material for other tris(formamidinato)diruthenium complexes. The syntheses and crystal structures of 1 . HDPhF, 1 . 2thf, and [Ru2Cl(mu-O2CC6H4OC10H21)(mu-DPhF)(3)] (2) are reported. (C) 2003 Elsevier B.V. All rights reserved.

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页码：42 / 46

页数：5

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