Synthesis and characterization of the diruthenium(III) complexes Ru2(F4Oap)2(F5ap)2 and Ru2(F4Oap)(F4NCNap)(F5ap)2 where F4Oap is the 2-(3,4,5,6-tetrafluoro-2-oxoanilino)pyridinate anion, F4NCNap is the 2-(3,4,5,6-tetrafluoro-2-cyanamidoanilino)pyridinate anion, and F5ap is the 2-(2,3,4,5,6-pentafluoroanilino)pyridinate anion

被引：21

作者：

Bear, JL ^{[1
]}

Li, YL ^{[1
]}

Han, BC ^{[1
]}

Van Caemelbecke, E ^{[1
]}

Kadish, KM ^{[1
]}

机构：

[1] Univ Houston, Dept Chem, Houston, TX 77204 USA

来源：

INORGANIC CHEMISTRY | 2001年 / 40卷 / 01期

关键词：

D O I：

10.1021/ic991505x

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two diruthenium(III) complexes with mixed anionic bridging ligands are synthesized and characterized as to their structural, electrochemical, and spectroscopic properties. Both compounds undergo not only metal-centered but also ligand-centered electrode reactions and this is accounted for by their quinone-type structures.

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页码：182 / +

页数：6

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