Ultra narrow PbS nanorods with lntense fluorescence

被引:87
作者
Acharya, Somobrata [1 ]
Gautam, Ujjal K. [2 ]
Sasaki, Toshio [1 ]
Bando, Yoshio [1 ,2 ]
Golan, Yuval [4 ,5 ]
Ariga, Katsuhiko [3 ]
机构
[1] Natl Inst Mat Sci, Int Ctr Young Sci, Tsukuba, Ibaraki 3050044, Japan
[2] Natl Inst Mat Sci, Nanoscale Mat Ctr, Tsukuba, Ibaraki 3050044, Japan
[3] Natl Inst Mat Sci, Supermol Grp, Tsukuba, Ibaraki 3050044, Japan
[4] Ben Gurion Univ Negev, Dept Mat Engn, IL-84105 Beer Sheva, Israel
[5] Ben Gurion Univ Negev, Ilse Katz Inst Meso & Nanoscale Sci & Technol, IL-84105 Beer Sheva, Israel
关键词
D O I
10.1021/ja711064b
中图分类号
O6 [化学];
学科分类号
0703 [化学];
摘要
We report on the narrowest "free" quantum rods of PbS with 1.7 nm diameter produced in a single step under bench-top reaction conditions. The nanorods exhibit molecule-like discrete narrow optical behavior with high fluorescence quantum yield. We propose a new macroscopic vortex assembly formation by simple spin casting route. Interestingly, the pattern generates fluorescence along its line from the nanorod domains. The ultra narrow nanorods with strong discrete fluorescence and robust stability could be useful in biological labeling, fluorescence resonance energy transfer, and optoelectronics; applications, as well as to verify the theories in the very strong confinement regime.
引用
收藏
页码:4594 / +
页数:3
相关论文
共 22 条
[1]
Polarization properties and switchable assembly of ultranarrow ZnSe nanorods [J].
Acharya, Somobrata ;
Panda, Asit B. ;
Efrima, Shlomo ;
Golan, Ynval .
ADVANCED MATERIALS, 2007, 19 (08) :1105-1108
[2]
Switchable assembly of ultra narrow CdS nanowires and nanorods [J].
Acharya, Somobrata ;
Patla, Israel ;
Kost, Joseph ;
Efrima, Shlomo ;
Golan, Yuval .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (29) :9294-9295
[3]
PbS quantum dots with stable efficient luminescence in the near-IR spectral range [J].
Bakueva, L ;
Gorelikov, I ;
Musikhin, S ;
Zhao, XS ;
Sargent, EH ;
Kumacheva, E .
ADVANCED MATERIALS, 2004, 16 (11) :926-929
[4]
Designing PbSe nanowires and nanorings through oriented attachment of nanoparticles [J].
Cho, KS ;
Talapin, DV ;
Gaschler, W ;
Murray, CB .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (19) :7140-7147
[5]
Optical properties of colloidal PbSe nanocrystals [J].
Du, H ;
Chen, CL ;
Krishnan, R ;
Krauss, TD ;
Harbold, JM ;
Wise, FW ;
Thomas, MG ;
Silcox, J .
NANO LETTERS, 2002, 2 (11) :1321-1324
[6]
DUAN X, 2003, SCIENCE, V421, P241
[7]
Colloidal PbS nanocrystals with size-tunable near-infrared emission: Observation of post-synthesis self-narrowing of the particle size distribution [J].
Hines, MA ;
Scholes, GD .
ADVANCED MATERIALS, 2003, 15 (21) :1844-1849
[8]
Observation of coupled vibrational modes of a semiconductor nanocrystal [J].
Krauss, TD ;
Wise, FW ;
Tanner, DB .
PHYSICAL REVIEW LETTERS, 1996, 76 (08) :1376-1379
[9]
Raman-scattering study of exciton-phonon coupling in PbS nanocrystals [J].
Krauss, TD ;
Wise, FW .
PHYSICAL REVIEW B, 1997, 55 (15) :9860-9865
[10]
Single-crystalline star-shaped nanocrystals and their evolution: Programming the geometry of nano-building blocks [J].
Lee, SM ;
Jun, YW ;
Cho, SN ;
Cheon, J .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (38) :11244-11245