The influence of cyanide on the carbonylation of iron(II): Synthesis of Fe-SR-CN-CO centers related to the hydrogenase active sites

被引:70
作者
Rauchfuss, TB [1 ]
Contakes, SM [1 ]
Hsu, SCN [1 ]
Reynolds, MA [1 ]
Wilson, SR [1 ]
机构
[1] Univ Illinois, Dept Chem, Urbana, IL 61801 USA
关键词
D O I
10.1021/ja015948n
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
引用
收藏
页码:6933 / 6934
页数:2
相关论文
共 29 条
[1]   Primordial carbonylated iron-sulfur compounds and the synthesis of pyruvate [J].
Cody, GD ;
Boctor, NZ ;
Filley, TR ;
Hazen, RM ;
Scott, JH ;
Sharma, A ;
Yoder, HS .
SCIENCE, 2000, 289 (5483) :1337-1340
[2]   Synthesis and structure of a thiolate-bridged nickel-iron complex: towards a mimic of the active site of NiFe-hydrogenase [J].
Davies, SC ;
Evans, DJ ;
Hughes, DL ;
Longhurst, S ;
Sanders, JR .
CHEMICAL COMMUNICATIONS, 1999, (19) :1935-1936
[3]   FTIR characterization of the active site of the Fe-hydrogenase from Desulfovibrio desulfuricans [J].
De Lacey, AL ;
Stadler, C ;
Cavazza, C ;
Hatchikian, EC ;
Fernandez, VM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (45) :11232-11233
[4]   Nickel-iron-sulfur active sites: Hydrogenase and co dehydrogenase [J].
Fontecilla-Camps, JC ;
Ragsdale, SW .
ADVANCES IN INORGANIC CHEMISTRY, VOL 47, 1999, 47 :283-333
[5]   SYNTHESIS, CRYSTAL-STRUCTURE, ELECTROCHEMISTRY AND ELECTRONIC PARAMAGNETIC-RESONANCE SPECTROSCOPY OF [M((PPH2CH2)3CME)(O-S2C6H4)][PF6]N (M=FE, CO OR RH, N=0 OR 1) [J].
GHILARDI, CA ;
LASCHI, F ;
MIDOLLINI, S ;
ORLANDINI, A ;
SCAPACCI, G ;
ZANELLO, P .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1995, (04) :531-540
[6]   UBER METALLCARBONYLE .55. ZUR KENNTNIS DER CARBONYLCYANOKOMPLEXE VON EISEN UND KOBALT [J].
HIEBER, W ;
NAST, R ;
BARTENSTEIN, C .
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1953, 272 (1-4) :32-39
[7]   Chemistry of iron thiolate complexes with CN- and CO. Models for the [Fe(CO)(CN)(2)] structural unit in Ni-Fe hydrogenase enzymes [J].
Hsu, HF ;
Koch, SA ;
Popescu, CV ;
Munck, E .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (35) :8371-8372
[8]   Peptides by activation of amino acids with CO on (Ni,Fe)S surfaces:: Implications for the origin of life [J].
Huber, C ;
Wächtershäuser, G .
SCIENCE, 1998, 281 (5377) :670-672
[9]   Activated acetic acid by carbon fixation on (Fe,Ni)S under primordial conditions [J].
Huber, C ;
Wachtershauser, G .
SCIENCE, 1997, 276 (5310) :245-247
[10]  
JIANG J, 2001, 221 NAT M AM CHEM SO, P525