Synthesis and structure of a thiolate-bridged nickel-iron complex: towards a mimic of the active site of NiFe-hydrogenase

被引：73

作者：

Davies, SC ^{[1
]}

Evans, DJ ^{[1
]}

Hughes, DL ^{[1
]}

Longhurst, S ^{[1
]}

Sanders, JR ^{[1
]}

机构：

[1] John Innes Ctr Plant Sci Res, Dept Biol Chem, Norwich NR4 7UH, Norfolk, England

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 19期

关键词：

D O I：

10.1039/a905353k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction, under carbon monoxide, of [Fe(NS3)(CO)](-) [NS3 = N(CH2CH2S)(3)(3-)] with [NiCl2(dppe)] gives the structurally characterised dinuclear thiolate-bridged complex [{Fe(NS3)(CO)(2)-S,S'}NiCl(dppe)], which has structural features similar to those of the active site of NiFe-hydrogenase.

引用

页码：1935 / 1936

页数：2

共 15 条

[1] A hybrid density functional theory molecular mechanics study of nickel-iron hydrogenase: Investigation of the active site redox states
Amara, P
Volbeda, A
Fontecilla-Camps, JC
Field, MJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (18) : 4468 - 4477
[2] SYNTHESIS AND STRUCTURE OF A NI3FE CLUSTER FEATURING SINGLE AND DOUBLE THIOLATO BRIDGES
COLPAS, GJ
DAY, RO
MARONEY, MJ
[J]. INORGANIC CHEMISTRY, 1992, 31 (24) : 5053 - 5055
[3] Vanadium complexes of the N(CH2CH2S)(3)(3-)-ligand with co-ligands relevant to nitrogen fixation processes
Davies, SC
Hughes, DL
Janas, Z
Jerzykiewicz, L
Richards, RL
Sanders, JR
Sobota, P
[J]. CHEMICAL COMMUNICATIONS, 1997, (14) : 1261 - 1262
[4] Iron complexes of the N(CH2CH2S)33- ligand;: a paramagnetic, trigonal bipyramidal Fe(II) CO complex as a chelate ligand
Davies, SC
Hughes, DL
Richards, RL
Sanders, JR
[J]. CHEMICAL COMMUNICATIONS, 1998, (24) : 2699 - 2700
[5] Ni-Fe hydrogenases: A density functional theory study of active site models
De Gioia, L
Fantucci, P
Guigliarelli, B
Bertrand, P
[J]. INORGANIC CHEMISTRY, 1999, 38 (11) : 2658 - 2662
[6] EVANS D, UNPUB
[7] Thiolate bridged nickel-iron complexes containing both iron(0) and iron(II) carbonyls
Lai, CH
Reibenspies, JH
Darensbourg, MY
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1996, 35 (20): : 2390 - 2393
[8] MILLS DK, 1991, J AM CHEM SOC, V113, P421
[9] Theoretical characterization, of the reaction intermediates in a model of the nickel-iron hydrogenase of Desulfovibrio gigas
Niu, SQ
Thomson, LM
Hall, MB
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (16) : 4000 - 4007
[10] Synthesis, X-ray structure and electrochemical characterisation of a binuclear thiolate bridged Ni-Fe-nitrosyl complex, related to the active site of NiFe hydrogenase
Osterloh, F
Saak, W
Haase, D
Pohl, S
[J]. CHEMICAL COMMUNICATIONS, 1997, (10) : 979 - 980

← 1 2 →