Synthesis and structure of a thiolate-bridged nickel-iron complex: towards a mimic of the active site of NiFe-hydrogenase

被引：73

作者：

Davies, SC ^{[1
]}

Evans, DJ ^{[1
]}

Hughes, DL ^{[1
]}

Longhurst, S ^{[1
]}

Sanders, JR ^{[1
]}

机构：

[1] John Innes Ctr Plant Sci Res, Dept Biol Chem, Norwich NR4 7UH, Norfolk, England

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 19期

关键词：

D O I：

10.1039/a905353k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction, under carbon monoxide, of [Fe(NS3)(CO)](-) [NS3 = N(CH2CH2S)(3)(3-)] with [NiCl2(dppe)] gives the structurally characterised dinuclear thiolate-bridged complex [{Fe(NS3)(CO)(2)-S,S'}NiCl(dppe)], which has structural features similar to those of the active site of NiFe-hydrogenase.

引用

页码：1935 / 1936

页数：2

共 15 条

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