The coordination chemistry of the hydrotris(3-diphenylmethylpyrazol-1-yl)borate (TpCHPh2) ligand

被引：20

作者：

Rheingold, AL ^{[1
]}

Liable-Sands, LM ^{[1
]}

Golen, JA ^{[1
]}

Yap, GPA ^{[1
]}

Trofimenko, S ^{[1
]}

机构：

[1] Univ Delaware, Dept Chem & Biochem, Newark, DE 19716 USA

来源：

DALTON TRANSACTIONS | 2004年 / 04期

关键词：

D O I：

10.1039/b313785f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new ligand, hydrotris[3-(diphenylmethyl) pyrazol-1-yl]borate, Tp(CHPh 2), has been synthesized and its coordination chemistry was compared with that of the analogous Tp(iPr). The new ligand was converted to a variety of complexes, such as M[Tp(CHPh 2)]X(M=Co, Ni, Zn; X=Cl, NCO, NCS), Pd[Tp(CHPh2) ][eta(3)-methallyl], Co[Tp(CHPh 2)](acac), and Co[Tp(CHPh 2)](scorpionate ligand). Compounds Tl[Tp(CHPh 2)], 1, Co[Tp(CHPh 2)]Cl, 2, Co[Tp(CHPh 2)](NCS)(DMF), 3, Ni[Tp(CHPh 2)](NCS)(DMF)(2), 4, Co[Tp(CHPh 2)](acac), 5, Co[Tp(CHPh 2)][Ph(2)Bp], 6, Co[Tp(CHPh 2)][Bp(Ph)], 7, Co[Tp(CHPh 2)][Tp], 8, and (Ni[Tp(CHPh 2)])(2)[C2O4](H2O)(2), 9, were structurally characterized.

引用

页码：598 / 604

页数：7

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