[Cp(η2-bipy)(MeCN)RuII][PF6] catalysts for regioselective allylic substitution and characterization of dicationic [Cp(η2-bipy)(η3-allyl)RuIV][PF6]2 intermediates

被引：110

作者：

Mbaye, MD

Demerseman, B ^{[1
]}

Renaud, JL

Toupet, L

Bruneau, C

机构：

[1] Univ Rennes 1, Inst Chim, CNRS, UMR 6509, F-35042 Rennes, France

[2] Univ Rennes 1, Inst Chim Rennes 1, CNRS, UMR 6626,Grp Mat Condensee & Mat, F-35042 Rennes, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 41期

关键词：

allyl complexes; homogeneous catalysis; ligand effects; N ligands; ruthenium;

D O I：

10.1002/anie.200352257

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The coordination of a 2,2′-bipyridyl derivative to a (C 5Me5)RuII fragment provides both a facile route to unprecedented dicationic (allyl)RuIV complexes (see picture) and new highly efficient catalysts for the regioselective allylic substitution from unsymmetrical allylic carbonates.

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收藏

页码：5066 / 5068

页数：3

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