Synthesis of large-area three-dimensional polyaniline nanowire networks using a "soft template"

被引:90
作者
Zhong, WB
Deng, JY
Yang, YS
Yang, WT [1 ]
机构
[1] Minist Educ, Key Lab Sci & Technol Controllable Chem React, Beijing 100029, Peoples R China
[2] Beijing Univ Chem Technol, Dept Polymer Sci, Beijing 100029, Peoples R China
关键词
cationic emulsifier; organic diacid; polyaniline; three-dimensional nanowire networks;
D O I
10.1002/marc.200400463
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Three-dimensional polyaniline (PANI) nanowire networks were synthesized in high yield using a "soft template" self-assembled with hexadecyltrimethylammonium bromide and oxalic acid. The PANI nanowire networks had diameters from 35-100 nm depending on synthesis conditions and/or procedures. The networks and the "cross-linking points" were clearly observed by field-emission scanning electron microscopy and transmission electron microscopy. A possible mechanism for the formation of three-dimensional PANI nanowire networks is discussed.
引用
收藏
页码:395 / 400
页数:6
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