Silver Triflate Catalyzed Acetylation of Alcohols, Thiols, Phenols, and Amines

被引:45
作者
Das, Rima [1 ]
Chakraborty, Debashis [1 ]
机构
[1] Indian Inst Technol Madras, Dept Chem, Madras 600036, Tamil Nadu, India
来源
SYNTHESIS-STUTTGART | 2011年 / 10期
关键词
acetylation; silver triflate; alcohol; phenol; thiol; amine; ACETIC-ANHYDRIDE; EFFICIENT CATALYST; HIGHLY EFFICIENT; PRACTICAL ACYLATION; ACID ANHYDRIDES; ZINC-OXIDE; POWERFUL; CHLORIDE; MILD; 4-DIALKYLAMINOPYRIDINES;
D O I
10.1055/s-0030-1259999
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A variety of alcohols, thiols, phenols, and amines were subjected to acetylation reaction using acetic anhydride in the presence of catalytic quantity of silver triflate. The method described has a wide range of applications, proceeds under mild conditions, does not involve cumbersome workup, and the resulting products are obtained in high yields within a reasonable time.
引用
收藏
页码:1621 / 1625
页数:5
相关论文
共 39 条
[1]   Molecular iodine in isopropenyl acetate (IPA): a highly efficient catalyst for the acetylation of alcohols, amines and phenols under solvent free conditions [J].
Ahmed, Naseem ;
van Lier, Johan E. .
TETRAHEDRON LETTERS, 2006, 47 (30) :5345-5349
[2]  
Baker R.H., 1955, ORG SYNTHESES, V3, P141
[3]  
Bandgar BP, 2002, SYNLETT, P735
[4]  
Bartoli G, 2003, SYNLETT, P39
[5]   Zirconium(IV) chloride as a new, highly efficient, and reusable catalyst for acetylation of phenols, thiols, amines, and alcohols under solvent-free conditions [J].
Chakraborti, AK ;
Gulhane, R .
SYNLETT, 2004, (04) :627-630
[6]   Fluoroboric acid adsorbed on silica gel as a new and efficient catalyst for acylation of phenols, thiols, alcohols, and amines [J].
Chakraborti, AK ;
Gulhane, R .
TETRAHEDRON LETTERS, 2003, 44 (17) :3521-3525
[7]   Silver nitrate-catalyzed oxidation of aldehydes to carboxylic acids by H2O2 [J].
Chakraborty, Debashis ;
Gowda, Ravikumar R. ;
Malik, Payal .
TETRAHEDRON LETTERS, 2009, 50 (47) :6553-6556
[8]  
Chandrasekhar S, 2004, INDIAN J CHEM B, V43, P813
[9]  
Chauhan KK, 1999, SYNLETT, P1743
[10]  
Cope A.C., 1963, ORG SYNTH, V4, P304