Synthetic strategies toward buckybowls and C60:: benzannulation is remarkably facile compared to cyclopentannulation

被引：10

作者：

Dinadayalane, TC ^{[1
]}

Sastry, GN ^{[1
]}

机构：

[1] Pondicherry Univ, Dept Chem, Pondicherry 605014, India

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 36期

关键词：

pinakene; strain energy; buckybowl; theoretical calculations; synthetic strategy;

D O I：

10.1016/S0040-4039(01)01268-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Computations on a model buckybowl, pinakene (C28H14) unequivocally predict that in general, benzannulation is a significantly facile process compared to cyclopentannulation in the ring closure synthetic strategy towards buckybowls. (C) 2001 Published by Elsevier Science Ltd.

引用

页码：6421 / 6423

页数：3

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