[RuCl3(H2O)n]-catalyzed direct arylations

被引：112

作者：

Ackermann, Lutz ^{[1
]}

Althammer, Andreas ^{[1
]}

Born, Robert ^{[1
]}

机构：

[1] Univ Gottingen, Inst Organ & Biomol Chem, D-37077 Gottingen, Germany

来源：

TETRAHEDRON | 2008年 / 64卷 / 26期

关键词：

D O I：

10.1016/j.tet.2008.01.050

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Catalytic amounts of economically attractive [RuCl3(H2O)(n)] allow for direct arylations via C-H bond functionalization with aryl bromides under phosphine ligand-free reaction conditions. Thereby, a variety of functionalized (hetero)aryl bromides, bearing either electron-withdrawing or electron-releasing substituents, can be employed for direct arylations of pyridine, oxazoline, pyrazole, or ketimine derivatives as pronucleophiles. (C) 2008 Elsevier Ltd. All rights reserved.

引用

页码：6115 / 6124

页数：10

共 57 条

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