A diaminochlorophosphine for palladium-catalyzed arylations of amines and ketones

被引：95

作者：

Ackermann, Lutz ^{[1
]}

Spatz, Julia H. ^{[1
]}

Gschrei, Christian J. ^{[1
]}

Born, Robert ^{[1
]}

Althammer, Andreas ^{[1
]}

机构：

[1] Univ Munich, Dept Chem & Biochem, D-81377 Munich, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 45期

关键词：

arylation; C-N coupling; cross-coupling; palladium; phosphane ligands;

D O I：

10.1002/anie.200602222

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Sterically hindered substituents on a secondary chlorophosphine 1 prevent formation of a diaminooxophosphine, and thereby allow for highly efficient arylation reactions of amines and α-C-H acidic ketones with (hetero)aryl chlorides. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：7627 / 7630

页数：4

共 35 条

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