Determination of activation and deactivation rate constants of model compounds in atom transfer radical polymerization

被引：178

作者：

Matyjaszewski, K ^{[1
]}

Paik, HJ ^{[1
]}

Zhou, P ^{[1
]}

Diamanti, SJ ^{[1
]}

机构：

[1] Carnegie Mellon Univ, Dept Chem, Ctr Macromol Engn, Pittsburgh, PA 15213 USA

来源：

MACROMOLECULES | 2001年 / 34卷 / 15期

关键词：

D O I：

10.1021/ma010185+

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The activation and deactivation rate constants in atom transfer radical polymerization (ATRP) were measured using model compounds. The activation rate constants were determined using HPLC or GC under the kinetic isolation condition achieved by trapping the generated radical with 2,2,6,6-tetramethylpiperidinyl-1-oxy (TEMPO). The deactivation rate constants were measured by trapping 1-phenylethyl radicals with TEMPO in a competitive reaction. The effects of several parameters in ATRP systems were examined, including alkyl groups, ligands, transferred groups, and solvents. The data obtained were consistent with ATRP kinetics and provided further quantitative insights into understanding the ATRP processes.

引用

页码：5125 / 5131

页数：7

共 51 条

[21] Controlled/''living'' radical polymerization. Kinetics of the homogeneous atom transfer radical polymerization of styrene [J].