Modification of montmorillonite with oligomeric amine derivatives for polymer nanocomposite preparation

被引：53

作者：

Yoon, Keun-byoung ^{[1
]}

Sung, Ho-dong ^{[1
]}

Hwang, Young-young ^{[1
]}

Noh, Seok Kyun ^{[2
]}

Lee, Dong-ho ^{[1
]}

机构：

[1] Kyungpook Natl Univ, Dept Polymer Sci, Coll Engn, Taegu 702701, South Korea

[2] Yeungnam Univ, Sch Chem Engn & Technol, Kyongsan 712749, South Korea

来源：

APPLIED CLAY SCIENCE | 2007年 / 38卷 / 1-2期

关键词：

montmorillonite; oligomeric amine modifiers; polyoxypropylenediamine; nanocomposites;

D O I：

10.1016/j.clay.2007.01.003

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Sodium montmorillonite (Na-MMT) was modified with oligomeric polyoxypropylene amine derivatives as well as simple amines by a cation exchange. For reference, commercial modified MMTs, Cloisite (TM) were analyzed in detail. The modifier content in OA-MMT as determined by TGA was found to be 4 - 40 wt.% and dependent on the structure of the modifier. The basal spacing of OA-MMT was strongly dependent on the structure and amount of the modifier. With the polyoxypropylenediamine of molecular mass 2000, the basal spacing of OA-MMT was enlarged up to 45.3 angstrom. The OA-MMT nanocomposites with polystyrene (PS) and poly(methyl methacrylate) (PMMA) were prepared by solution blending and in-situ polymerization, a large extent of exfoliation was obtained, together with thin packets of montmorillonite layers. (c) 2007 Elsevier B.V. All rights reserved.

引用

页码：1 / 8

页数：8