Responsive lanthanide luminescent cyclen complexes: from switching/sensing to supramolecular architectures

被引：279

作者：

Gunnlaugsson, T ^{[1
]}

Leonard, JP ^{[1
]}

机构：

[1] Univ Dublin Trinity Coll, Dept Chem, Dublin 2, Ireland

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 25期

关键词：

D O I：

10.1039/b418196d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This article highlights some of the recent developments in the use of responsive cyclen based lanthanide luminescent devices, focusing on Eu(III), Tb(III), Nd(III) and Yb(III) complexes, where the photophysical properties, such as the excited state lifetimes, quantum yield/intensity and emission polarisation are modulated by the local chemical environment, e. g. ions and molecules, or through self-assembly of either f-f or mixed f-d cyclen complexes.

引用

页码：3114 / 3131

页数：18

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