Rapid synthesis and size control of CuInS2 semi-conductor nanoparticles using microwave irradiation

被引：78

作者：

Gardner, Joseph S. ^{[1
]}

Shurdha, Endrit ^{[1
]}

Wang, Chongmin ^{[2
]}

Lau, Lisa D. ^{[1
]}

Rodriguez, Rene G. ^{[1
]}

Pak, Joshua J. ^{[1
]}

机构：

[1] Idaho State Univ, Dept Chem, Pocatello, ID 83209 USA

[2] Pacific NW Natl Lab, WR Wiley Environm Mol Sci Lab, Richland, WA 99352 USA

来源：

JOURNAL OF NANOPARTICLE RESEARCH | 2008年 / 10卷 / 04期

基金：

美国国家科学基金会;

关键词：

microwave irradiation; size-control; CuInS2; ternary; nanoparticle semi-conductor; colloids;

D O I：

10.1007/s11051-007-9294-7

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The properties of CuInS2 semi-conductor nanoparticles make them attractive materials for use in next-generation photovoltaics. We have prepared CuInS2 nanoparticles from single source precursors via microwave irradiation. Microwave irradiation methods have allowed us to increase the efficiency of preparation of these materials by providing uniform heating and rapid reaction times. The synergistic effect of varying thiol capping ligand concentrations as well as reaction temperatures and times resulted in fine control of nanoparticle growth in the 3-5 nm size range. Investigation of the photophysical properties of the colloidal nanoparticles were performed using electronic absorption and luminescence emission spectroscopy. Qualitative nanoparticles sizes were determined from the photoluminescence (PLE) data and compared to HRTEM images.

引用

页码：633 / 641

页数：9

共 30 条

[11] A facile route to the synthesis of CuInS2 nanoparticles [J].

Dutta, Dimple P. ;

Sharma, Garima .

MATERIALS LETTERS, 2006, 60 (19) :2395-2398

[12] Microwave-assisted alkaline digestion combined with microwave-assisted distillation for the determination of iodide and total iodine in edible seaweed by catalytic spectrophotometry [J].

Gamallo-Lorenzo, D ;

Barciela-Alonso, MD ;

Moreda-Piñeiro, A ;

Bermejo-Barrera, A ;

Bermejo-Barrera, P .

ANALYTICA CHIMICA ACTA, 2005, 542 (02) :287-295

[13] Green chemistry: Efficient epoxides ring-opening with 1-butanol under microwave irradiation [J].

Garcia-Vidal, Jesus A. ;

Duran-Valle, Carlos J. ;

Ferrera-Escudero, Santiago .

APPLIED SURFACE SCIENCE, 2006, 252 (17) :6064-6066

[14] Microwave-enhanced reaction rates for nanoparticle synthesis [J].

Gerbec, JA ;

Magana, D ;

Washington, A ;

Strouse, GF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (45) :15791-15800

[15] Microwave-assisted polyol synthesis of CulnTe2 and CulnSe2 nanoparticles [J].

Grisaru, H ;

Palchik, O ;

Gedanken, A ;

Palchik, V ;

Slifkin, MA ;

Weiss, AM .

INORGANIC CHEMISTRY, 2003, 42 (22) :7148-7155

[16] SYNTHESIS OF MIXED COPPER INDIUM CHALCOGENOLATES - SINGLE-SOURCE PRECURSORS FOR THE PHOTOVOLTAIC MATERIALS CUINQ2 (Q=S, SE) [J].

HIRPO, W ;

DHINGRA, S ;

SUTORIK, AC ;

KANATZIDIS, MG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (04) :1597-1599

[17] Ligand effects on optical properties of CdSe nanocrystals [J].

Kalyuzhny, G ;

Murray, RW .

JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (15) :7012-7021

[18] Synthesis and characterization of indium oxide nanoparticles [J].

Murali, A ;

Barve, A ;

Leppert, VJ ;

Risbud, SH ;

Kennedy, IM ;

Lee, HWH .

NANO LETTERS, 2001, 1 (06) :287-289

[19] Preparation of ultrafine chalcopyrite nanoparticles via the photochemical decomposition of molecular single-source precursors [J].

Nairn, Justin J. ;

Shapiro, Pamela J. ;

Twamley, Brendan ;

Pounds, Tyler ;

von Wandruszka, Ray ;

Fletcher, T. Rick ;

Williams, Mark ;

Wang, Chongmin ;

Norton, M. Grant .

NANO LETTERS, 2006, 6 (06) :1218-1223

[20] Optimisation of microwave assisted digestion of sediments and determination of Sn and Hg [J].

Navarro, P ;

Raposo, JC ;

Arana, G ;

Etxebarria, N .

ANALYTICA CHIMICA ACTA, 2006, 566 (01) :37-44

← 1 2 3 →