Evidence of asymmetric autocatalysis in the enantioselective addition of diisopropylzinc to pyrimidine-5-carbaldehyde using chiral pyrimidyl alkanol

被引：69

作者：

Sato, I

Omiya, D

Tsukiyama, K ^{[1
]}

Ogi, Y

Soai, K

机构：

[1] Tokyo Univ Sci, Fac Sci, Dept Appl Chem, Shinjuku Ku, Tokyo 1628601, Japan

[2] Tokyo Univ Sci, Fac Sci, Dept Chem, Shinjuku Ku, Tokyo 1628601, Japan

来源：

TETRAHEDRON-ASYMMETRY | 2001年 / 12卷 / 14期

关键词：

D O I：

10.1016/S0957-4166(01)00351-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Kinetic analysis of the relationship between the reaction time and the yields of the product in the enantioselective addition of diisopropylzinc to pyrimidine-5-carbaldehyde using chiral pyrimidyl alkanol proves that the reaction is autocatalytic. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：1965 / 1969

页数：5

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