NONLINEAR EFFECTS IN ASYMMETRIC CATALYSIS

被引：371

作者：

GUILLANEUX, D ^{[1
]}

ZHAO, SH ^{[1
]}

SAMUEL, O ^{[1
]}

RAINFORD, D ^{[1
]}

KAGAN, HB ^{[1
]}

机构：

[1] UNIV PARIS 11, INST CHIM MOLEC ORSAY,CNRS,URA 1497, SYNTH ASYMETR LAB, F-91405 ORSAY, FRANCE

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1994年 / 116卷 / 21期

关键词：

D O I：

10.1021/ja00100a004

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Seemingly unusual phenomena may occur in asymmetric catalysis involving partially resolved ligands. Deviations from linearity (between the ee of the ligand and the ee of the product) are possible, and various cases are considered using simplified models. The fundamental features are highlighted in models taking into account diastereomeric associations inside (model 1) or outside (model 2) the catalytic cycle. Various cases found experimentally are considered.

引用

页码：9430 / 9439

页数：10

共 65 条

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