BETA-HYDROXY SULFOXIMINES AS CATALYSTS FOR THE ENANTIOSELECTIVE ALKYLATION OF ALDEHYDES

被引:50
作者
BOLM, C
MULLER, J
SCHLINGLOFF, G
ZEHNDER, M
NEUBURGER, M
机构
关键词
D O I
10.1039/c39930000182
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Optically active beta-hydroxy sulfoximines are catalysts for the enantioselective ethyl transfer from diethylzinc to aldehydes affording secondary alcohols with high enantioselectivity; the structure of a dimeric zinc alkoxide has been determined by X-ray diffraction analysis.
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页码:182 / 183
页数:2
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