BETA-HYDROXY SULFOXIMINES AS CATALYSTS FOR THE ENANTIOSELECTIVE ALKYLATION OF ALDEHYDES

被引：50

作者：

BOLM, C

MULLER, J

SCHLINGLOFF, G

ZEHNDER, M

NEUBURGER, M

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 02期

关键词：

D O I：

10.1039/c39930000182

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Optically active beta-hydroxy sulfoximines are catalysts for the enantioselective ethyl transfer from diethylzinc to aldehydes affording secondary alcohols with high enantioselectivity; the structure of a dimeric zinc alkoxide has been determined by X-ray diffraction analysis.

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页码：182 / 183

页数：2

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