Interaction of Carbene and Olefin Donors with [Cl2PN]3: Exploration of a Reductive Pathway toward (PN)3

被引：37

作者：

Al-Rafia, S. M. Ibrahim ^{[1
]}

Ferguson, Michael J. ^{[1
]}

Rivard, Eric ^{[1
]}

机构：

[1] Univ Alberta, Dept Chem, Edmonton, AB T6G 2G2, Canada

来源：

INORGANIC CHEMISTRY | 2011年 / 50卷 / 21期

基金：

加拿大自然科学与工程研究理事会; 加拿大创新基金会;

关键词：

COMPLEXES; CATIONS; PN; ADDUCT; P-4;

D O I：

10.1021/ic201812a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The iminophosphine-phosphazene [P-III-P-V] heterocyclic adduct [IPr center dot PN(PCl2N)(2)] was prepared via reduction of the cyclic phosphazene [Cl2PN](3) in the presence of the carbene donor IPr {IPr = [(HCNDipp)(2)C:], where Dipp = 2,6-(Pr2C6H3)-Pr-1}. By contrast, the treatment of [Cl2PN](3) with the N-heterocydic olefin IPr=CH2 yielded the olefin-grafted phosphazene ring [(IPr=CH)P(Cl)N(PCl2N)(2)].

引用

页码：10543 / 10545

页数：3

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