Synthesis of borirenes by photochemical borylene transfer from [(OC)5M=BN(SiMe3)2] (M = Cr, Mo) to alkynes

被引：91

作者：

Braunschweig, H ^{[1
]}

Herbst, T ^{[1
]}

Rais, D ^{[1
]}

Seeler, F ^{[1
]}

机构：

[1] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 45期

关键词：

alkynes; borirenes; boron; borylene complexes; photochemistry;

D O I：

10.1002/anie.200502524

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Light movements: Irradiation of terminal borylene complexes [(OC)5M=B-N(SiMe3)2] (M = Cr, Mo) at room temperature in the presence of alkynes allows access to various substituted borirenes - an unprecedented borylene transfer to main-group-element substrates (see scheme; B red, C white, N blue, Si yellow). © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：7461 / 7463

页数：3

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