2,2-Bis(3-allyl-4-hydroxyphenyl)hexafluoropropane and fluorosiloxane as coating materials for nerve agent sensors

被引：9

作者：

Bhadury, PS ^{[1
]}

Dubey, V ^{[1
]}

Singh, S ^{[1
]}

Saxena, C ^{[1
]}

机构：

[1] Def Res & Dev Estab, Synth Chem Div, Gwalior 474002, India

来源：

JOURNAL OF FLUORINE CHEMISTRY | 2005年 / 126卷 / 08期

关键词：

2,2-bis(3-allyl-4-hydroxyphenyl)hexafluoropropane; 2,2-bis(4-allyoxyphenyl)hexafluoropropane; DMF; piezoelectric detector; fluorinated siloxane;

D O I：

10.1016/j.jfluchem.2005.06.006

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A simpler technique for the synthesis of 2,2-bis(4-allyoxyphenyl)hexafluoropropane has been achieved from 4,4'-(hexafluoroisopropylidene)diphenol for obtaining 2,2-bis(3-allyl-4-hydroxyphenyl)hexafluoropropane. This monomer and its corresponding hybrid organic/ inorganic siloxane polymer are successfully used as a coating material for the detection of toxic chemical warfare agents. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：1252 / 1256

页数：5

共 12 条

[1] HYDROGEN-BONDING .18. GAS-LIQUID-CHROMATOGRAPHIC MEASUREMENTS FOR THE DESIGN AND SELECTION OF SOME HYDROGEN-BOND ACIDIC PHASES SUITABLE FOR USE AS COATINGS ON PIEZOELECTRIC SORPTION DETECTORS [J].

ABRAHAM, MH ;

HAMERTON, I ;

ROSE, JB ;

GRATE, JW .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1991, (09) :1417-1423

[2] Fluorine chemistry.: Part 2.: Synthesis and characterization of 2H-heptafluoropropane (HFC-227ea) [J].

Bhadury, PS ;

Singh, S ;

Sharma, M ;

Malhotra, RC ;

Sekhar, K .

CANADIAN JOURNAL OF CHEMISTRY, 2004, 82 (09) :1381-1385

[3] Fluorine chemistry - Wittig based synthesis of volatile organofluorine compounds [J].

Bhadury, PS ;

Singh, S ;

Sharma, M ;

Palit, M ;

Jaiswal, DK .

CANADIAN JOURNAL OF CHEMISTRY, 2004, 82 (07) :1186-1191

[4] Synthesis of 2-phenylperfluoropropene and 1,1,1,3,3,3-hexafluoro-2-phenylpropane [J].

Bhadury, PS ;

Pant, BP ;

Palit, M ;

Jaiswal, DK .

JOURNAL OF FLUORINE CHEMISTRY, 1997, 85 (02) :115-116

[5] Synthesis, characterisation and mass spectrometric fragmentation of O-(chlorodifluoroacylated) alcohols [J].

Bhadury, PS ;

Palit, M ;

Sharma, M ;

Raza, SK ;

Jaiswal, DK .

JOURNAL OF FLUORINE CHEMISTRY, 2002, 113 (01) :47-50

[6] Fluorinated phosphonium ylides: versatile in situ Wittig intermediates in the synthesis of hydrofluorocarbons [J].

Bhadury, PS ;

Palit, M ;

Sharma, M ;

Raza, SK ;

Jaiswal, DK .

JOURNAL OF FLUORINE CHEMISTRY, 2002, 116 (01) :75-80

[7]

Dubey V, 2004, J APPL POLYM SCI, V91, P3428, DOI [10.1002/app.13442, 10.1022/app.13442]

[8] SOLUBILITY INTERACTIONS AND THE DESIGN OF CHEMICALLY SELECTIVE SORBENT COATINGS FOR CHEMICAL SENSORS AND ARRAYS [J].

GRATE, JW ;

ABRAHAM, MH .

SENSORS AND ACTUATORS B-CHEMICAL, 1991, 3 (02) :85-111

[9] Hybrid organic/inorganic copolymers with strongly hydrogen-bond acidic properties for acoustic wave and optical sensors [J].

Grate, JW ;

Kaganove, SN ;

Patrash, SJ ;

Craig, R ;

Bliss, M .

CHEMISTRY OF MATERIALS, 1997, 9 (05) :1201-1207

[10] PIEZOELECTRIC SORPTION DETECTOR [J].

KING, WH .

ANALYTICAL CHEMISTRY, 1964, 36 (09) :1735-&

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