Hydrothermal growth of ferromagnetic Fe-doped TiO2 films

被引:16
作者
Chan, Kelvin Y. S. [1 ]
Goh, Gregory K. L. [1 ]
机构
[1] Inst Mat Res & Engn, Singapore 117602, Singapore
关键词
ferromagnetism; epitaxial; thin film; anatase; Fe-doped; hydrothermal;
D O I
10.1016/j.tsf.2007.07.068
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Polycrystalline Fe-doped TiO2 anatase films were deposited on (001) oriented SrTiO3 single crystal substrates at temperatures less than 200 degrees C from acidic aqueous solutions of titanyl sulfate and iron (III) nitrate. Epitaxial anatase TiO2 films were obtained when the films were annealed in air at 900 degrees C. Room-temperature ferromagnetic Fe-doped TiO2 thin films were obtained after repeated deposition and annealing steps. The observed saturation magnetization (> 0.28 mu(B)/Fe) could not be attributed to the presence of secondary phase magnetic iron oxides or iron clusters. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:5582 / 5585
页数:4
相关论文
共 26 条
[1]  
BERCIU M, 2001, PHYS REV LETT, V87
[2]   Epitaxial growth and properties of ferromagnetic co-doped TiO2 anatase [J].
Chambers, SA ;
Thevuthasan, S ;
Farrow, RFC ;
Marks, RF ;
Thiele, JU ;
Folks, L ;
Samant, MG ;
Kellock, AJ ;
Ruzycki, N ;
Ederer, DL ;
Diebold, U .
APPLIED PHYSICS LETTERS, 2001, 79 (21) :3467-3469
[3]   Low-temperature behaviour of haematite: susceptibility and magnetization increase on cycling through the Morin transition [J].
de Boer, CB ;
Mullender, TAT ;
Dekkers, MJ .
GEOPHYSICAL JOURNAL INTERNATIONAL, 2001, 146 (01) :201-216
[4]   Cracking and orientation of solution-deposited rutile TiO2 films [J].
Goh, GKL ;
Donthu, SK ;
Pallathadka, PK .
CHEMISTRY OF MATERIALS, 2004, 16 (15) :2857-2861
[5]   Cracking of low temperature solution deposited CeO2 thin films [J].
Goh, Gregory K. L. ;
Tay, Christine S. S. ;
Chan, Kelvin Y. S. ;
Gosvami, N. .
JOURNAL OF ELECTROCERAMICS, 2006, 16 (04) :575-579
[6]   Epitaxial growth of ferromagnetic Co:TiO2 thin films by co-sputtering [J].
Han, GC ;
Wu, YH ;
Tay, M ;
Li, KB ;
Guo, ZB ;
Chong, TC .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2004, 268 (1-2) :159-164
[7]   Direct formation of iron(III)-doped titanium oxide (anatase) by thermal hydrolysis and its structural property [J].
Hirano, M ;
Joji, T ;
Inagaki, M .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2004, 87 (01) :35-41
[8]   Co distribution in ferromagnetic rutile Co-doped TiO2 thin films grown by laser ablation on silicon substrates [J].
Hong, NH ;
Sakai, J ;
Prellier, W ;
Hassini, A .
APPLIED PHYSICS LETTERS, 2003, 83 (15) :3129-3131
[9]   Ferromagnetism induced by clustered Co in Co-doped anatase TiO2 thin films -: art. no. 017401 [J].
Kim, JY ;
Park, JH ;
Park, BG ;
Noh, HJ ;
Oh, SJ ;
Yang, JS ;
Kim, DH ;
Bu, SD ;
Noh, TW ;
Lin, HJ ;
Hsieh, HH ;
Chen, CT .
PHYSICAL REVIEW LETTERS, 2003, 90 (01)
[10]  
KIYAMA M, 1976, J JPN SOC POWDER POW, V22, P77