A series of long-chain lamellar hydrated copper(II) alkylsulfonates with different chain molecular assemblies

被引：14

作者：

Park, SH ^{[1
]}

Lee, CE ^{[1
]}

机构：

[1] Korea Univ, Inst Nano Sci, Seoul 136701, South Korea

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 15期

关键词：

D O I：

10.1039/b303106c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of copper(II) salts with n-alkylsulfonate anions yields light blue lamellar Cu(CnH2n+1SO3)(2) . zH(2)O displaying distinct (mono/bi-layer) chain packing with increasing alkyl chain lengths; This may be attributed to the amphiphilic nature of the surfactants, i.e., the hydrophilic sulfonate head groups, mediating the coordination, and H-bonding interactions, and the hydrophobic alkyl chains.

引用

页码：1838 / 1839

页数：2

共 40 条

[1] ALBERTI G, 1996, COMPREHENSIVE SUPRAM, V7, P1
[2] Intermolecular interactions in nonorganic crystal engineering
Braga, D
Grepioni, F
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 2000, 33 (09) : 601 - 608
[3] Crystal engineering and organometallic architecture
Braga, D
Grepioni, F
Desiraju, GR
[J]. CHEMICAL REVIEWS, 1998, 98 (04) : 1375 - 1405
[4] THE STRUCTURE OF COPPER(II) DODECYL-SULFATE TETRAHYDRATE
BRUSCHINI, CS
DREW, MGB
HUDSON, MJ
LYSSENKO, K
[J]. POLYHEDRON, 1995, 14 (20-21) : 3099 - 3106
[5] Crystal engineering of metal complexes based on charge-augmented double hydrogen-bond interactions between thiosemicarbazides and carboxylates
Burrows, AD
Mingos, DMP
White, AJP
Williams, DJ
[J]. CHEMICAL COMMUNICATIONS, 1996, (01) : 97 - 99
[6] Variation in the coordination mode of arenedisulfonates to copper(II): synthesis and structural characterization of six copper(II) arenedisulfonate complexes
Cai, JW
Chen, CH
Liao, CZ
Yao, JH
Hu, XP
Chen, XM
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2001, (07): : 1137 - 1142
[7] A novel supramolecular synthon for H-bonded coordination networks: syntheses and structures of extended 2-dimensional cadmium(II) arenedisulfonates
Cai, JW
Chen, CH
Feng, XL
Liao, CZ
Chen, XM
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2001, (16): : 2370 - 2375
[8] LAYERED METAL PHOSPHATES AND PHOSPHONATES - FROM CRYSTALS TO MONOLAYERS
CAO, G
HONG, HG
MALLOUK, TE
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1992, 25 (09) : 420 - 427
[9] Synthesis and crystal structures of four nickel(II) 1,5-naphthalenedisulfonate compounds
Chen, CH
Cai, JW
Feng, XL
Chen, XM
[J]. JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2001, 31 (05) : 271 - 280
[10] Intercalation of alcohols in Ag sulfonates:: Topotactic behavior despite flexible layers
Côté, AP
Ferguson, MJ
Khan, KA
Enright, GD
Kulynych, AD
Dalrymple, SA
Shimizu, GKH
[J]. INORGANIC CHEMISTRY, 2002, 41 (02) : 287 - 292

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