Characterization of manganese-gallium mixed oxide powders

被引：12

作者：

Escribano, VS

López, EF

Huidobro, PS

Panizza, M

Resini, C

Gallardo-Amores, JM

Busca, G

机构：

[1] Univ Salamanca, Dept Quim Inorgan, E-37008 Salamanca, Spain

[2] Univ Genoa, Dipartimento Ingn Chim & Proc, I-16129 Genoa, Italy

[3] Univ Complutense, Lab Complutense Atlas Presiones, Dept Quim Inorgan, E-28040 Madrid, Spain

来源：

SOLID STATE SCIENCES | 2003年 / 5卷 / 11-12期

关键词：

XRD; FT-IR; DR-UV-V; Mn-Ga; mixed oxides;

D O I：

10.1016/j.solidstatesciences.2003.09.005

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Mn-Ga mixed oxides have been prepared by coprecipitation of the corresponding oxo-hydroxides as powders and have been characterized in relation to their structural and optical properties. The materials have been characterized by XRD, TG-DTA, skeletal IR and UV-visibleNIR spectroscopies. Large solubility of Mn in the diaspore type alpha-GaOOH oxo-hydroxide has been found. The spinel related structures of hausmannite Mn3O4 and of beta-gallia present large reciprocal solubilities at least in a metastable form. At high temperature also bixbyite-type alpha-Mn2O3 solid solutions containing up to 20% at. Ga have been observed. (C) 2003 Elsevier SAS. All rights reserved.

引用

页码：1481 / 1489

页数：9

共 54 条

[11] ESR AND REFLECTANCE SPECTRA OF MANGANESE IN POLYCRYSTALLINE TIO2 (RUTILE) [J].