The use of soluble polymers to effect homogeneous catalyst separation and reuse

被引:85
作者
Bergbreiter, DE [1 ]
机构
[1] Texas A&M Univ, Dept Chem, College Stn, TX 77843 USA
基金
美国国家科学基金会;
关键词
green chemistry; recycling; polymer support; homogenous catalysis; separation;
D O I
10.1016/S0920-5861(98)00121-7
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The use of soluble polymeric ligands for homogeneous catalysts separation is reviewed with emphasis on work from the author's laboratory. Examples discussed include polyethylene-bound catalysts, poly(alkene oxide)-bound catalysts, poly(N-isopropylacrylamide)-bound catalysts, fluorous polymer-bound catalysts and amphoteric polymer-bound catalysts. The utility of these systems is also discussed in the broader context of polymer-supported catalysis and the advantages and limitations of soluble polymeric ligands are discussed in this context. (C) 1998 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:389 / 397
页数:9
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