Synthesis, characterization, and photoluminescence of isostructural Mn, Co, and Zn MOFs having a diamondoid structure with large tetrahedral cages and high thermal stability

被引:171
作者
Sun, DF [1 ]
Ma, SQ [1 ]
Ke, YX [1 ]
Petersen, TM [1 ]
Zhou, HC [1 ]
机构
[1] Miami Univ, Dept Chem & Biochem, Oxford, OH 45056 USA
基金
美国国家科学基金会;
关键词
D O I
10.1039/b502007g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Three novel Mn, Co, and Zn MOFs containing large tetrahedral cages have been prepared and are stable up to 400 degrees C; X- ray diffraction revealed the frameworks are isostructural having a diamondoid structure of "hourglass'' subunits connected by triangular carboxylate ligands.
引用
收藏
页码:2663 / 2665
页数:3
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