A rare-earth MOF series:: Fascinating structure, efficient light emitters, and promising catalysts

被引：156

作者：

Gandara, F. ^{[1
]}

de Andres, A. ^{[1
]}

Gomez-Lor, B. ^{[1
]}

Gutierrez-Puebla, E. ^{[1
]}

Iglesias, M. ^{[1
]}

Monge, M. A. ^{[1
]}

Proserpio, D. M. ^{[2
]}

Snejko, N. ^{[1
]}

机构：

[1] CSIC, Inst Ciencia Mat Madrid, Madrid, Spain

[2] Univ Milan, Dipartimento Chim Struttura & Stereochim Inorgan, Milan, Italy

来源：

CRYSTAL GROWTH & DESIGN | 2008年 / 8卷 / 02期

关键词：

D O I：

10.1021/cg700796m

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new family of rare-earth polymeric framework RPF-4 has been obtained and its structure solved from an intrinsically triple twinned crystal. The framework formed by a H-O bond free rare-earth matrix, with the Ln atoms separated in two directions, makes them very promising materials for light-emitting diodes. The properties of the materials as heterogeneous catalysts are reported, too. IR spectroscopy suggests the presence of a peroxo complex that acts as active species in the oxidation reaction.

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页码：378 / 380

页数：3

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