Formation of highly functionalized hydrindanes and hydroazulenes via polyene cyclization promoted by the cross conjugated α-carbomethoxy enone system

被引:5
作者
Liu, HJ [1 ]
Sun, D
Roa-Gutierrez, F
Shia, KS
机构
[1] Natl Tsing Hua Univ, Dept Chem, Hsinchu 30013, Taiwan
[2] Univ Alberta, Dept Chem, Edmonton, AB T6G 2G2, Canada
关键词
polyenes; cyclization; bicyclic aliphatic compounds; hydridanes; hydroazulenes; steroidal compounds;
D O I
10.2174/1570178054038966
中图分类号
O62 [有机化学];
学科分类号
070303 [有机化学]; 081704 [应用化学];
摘要
The polyene cyclization promoted by the cross conjugated alpha-carbomethoxy enone system has been successfully applied to facilitate the construction of the hydridane and hydroazulene framework containing a high level of functionalization.
引用
收藏
页码:364 / 366
页数:3
相关论文
共 12 条
[1]
ALAMI M, 1995, ORG SYNTH, V72, P135
[2]
BARTLETT PA, 1984, ASYMMETRIC SYNTHESIS, V3, P341
[3]
Devon T. K., 1971, HDB NATURALLY OCCURR, V2
[4]
JOHNSON WS, 1976, BIOORG CHEM, V5, P51, DOI 10.1016/0045-2068(76)90016-X
[5]
An efficient procedure for the synthesis of thiophene-containing polycyclic compounds via polyene cyclization promoted by the cross conjugated beta-keto ester system [J].
Liu, HJ ;
Tran, DDP .
TETRAHEDRON LETTERS, 1997, 38 (37) :6501-6504
[6]
Polyene cyclization promoted by the cross conjugated alpha-carbalkoxy enone system [J].
Liu, HJ ;
Sun, DQ ;
Shia, KS .
TETRAHEDRON LETTERS, 1996, 37 (45) :8073-8076
[7]
Intramolecular Friedel-Crafts alkylation promoted by the cross conjugated β-keto ester system.: An efficient approach to highly functionalized hydrophenanthrenes and hydrochrysenes. [J].
Liu, HJ ;
Tran, DDP .
TETRAHEDRON LETTERS, 1999, 40 (20) :3827-3830
[8]
Polyene cyclization promoted by the cross conjugated α-carbalkoxy enone system.: An efficient approach to highly functionalized decalins [J].
Liu, HJ ;
Sun, DQ ;
Shia, KS .
JOURNAL OF THE CHINESE CHEMICAL SOCIETY, 1999, 46 (03) :453-462
[9]
Polyene cyclization promoted by the cross conjugated alpha-carbalkoxy enone system. Application to the total synthesis of (+/-)-dehydrochamaecynenol [J].
Liu, HJ ;
Sun, DQ .
TETRAHEDRON LETTERS, 1997, 38 (35) :6159-6162
[10]
Sutherland J. K., 1991, COMP ORG SYNTH, V1, P341