Electrodeposition of hydroxyapatite coating on AZ91D magnesium alloy for biomaterial application

被引:489
作者
Song, Y. W. [1 ]
Shan, D. Y. [1 ]
Han, E. H. [1 ]
机构
[1] Chinese Acad Sci, Inst Met Res, Environm Corros Ctr, Shenyang 110016, Peoples R China
关键词
deposition; hydroxyapatite; coating; biodegradable property; magnesium alloy;
D O I
10.1016/j.matlet.2008.02.048
中图分类号
T [工业技术];
学科分类号
08 [工学];
摘要
Magnesium and its alloys are potential biodegradable implant materials due to their attractive biological property. But their poor corrosion resistance may result in the sudden failure of the implants. The bioactive hydroxyapatite (HA) coating was electrodeposited on AZ91D magnesium alloy surface to improve its biodegradation performance. The biodegradable behavior of HA coating was investigated by electrochemical tests and immersion tests. The experimental results indicated that the as-deposited coating consisting of dicalcium phosphate dehydrate ((DCPD, CaHPO4 center dot 2H(2)O) and beta-tricalcium phosphate (beta-TCP, Ca-3 (PO4)(2)) was transformed into uniforryl hydroxyapatite (HA, Calo (PO4)(6)(OH)(2)) coating after immersion in 1 M NaOH solution for 2 h. The HA coating can obviously slow down the biodegradation rate of AZ91 D magnesium alloy in stimulated body fluid (SBF). (c) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:3276 / 3279
页数:4
相关论文
共 17 条
[1]
Biomaterial developments for bone tissue engineering [J].
Burg, KJL ;
Porter, S ;
Kellam, JF .
BIOMATERIALS, 2000, 21 (23) :2347-2359
[2]
Cao C., 2002, An Introduction to Electrochemical Impedance Spectroscopy, V1
[3]
Cao C.N., 2004, PRINCIPLE CORROSION
[4]
Characterization and corrosion studies of fluoride conversion coating on degradable Mg implants [J].
Chiu, K. Y. ;
Wong, M. H. ;
Cheng, F. T. ;
Man, H. C. .
SURFACE & COATINGS TECHNOLOGY, 2007, 202 (03) :590-598
[5]
Evaluation of cyto-toxicity and corrosion behavior of alkali-heat-treated magnesium in simulated body fluid [J].
Li, LC ;
Gao, JC ;
Wang, Y .
SURFACE & COATINGS TECHNOLOGY, 2004, 185 (01) :92-98
[6]
Corrosion behavior of AZ91 magnesium alloy treated by plasma immersion ion implantation and deposition in artificial physiological fluids [J].
Liu, Chenglong ;
Xin, Yunchang ;
Tian, Xiubo ;
Chu, Paul K. .
THIN SOLID FILMS, 2007, 516 (2-4) :422-427
[7]
Influence of heat treatment on degradation behavior of bio-degradable die-cast AZ63 magnesium alloy in simulated body fluid [J].
Liu, Chenglong ;
Xin, Yunchang ;
Tang, Guoyi ;
Chu, Paul K. .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2007, 456 (1-2) :350-357
[8]
Hydroxy apatite coatings on Ti-6Al-4V from seashell [J].
Narayanan, R ;
Dutta, S ;
Seshadri, SK .
SURFACE & COATINGS TECHNOLOGY, 2006, 200 (16-17) :4720-4730
[9]
Electrochemical nano-grained calcium phosphate coatings on Ti-6Al-4V for biomaterial applications [J].
Narayanan, R. ;
Seshadri, S. K. ;
Kwon, T. Y. ;
Kim, K. H. .
SCRIPTA MATERIALIA, 2007, 56 (03) :229-232
[10]
Bioactive calcium phosphate coating prepared on H2O2-treated titanium substrate by electrodeposition [J].
Park, JH ;
Lee, YK ;
Kim, KM ;
Kim, KN .
SURFACE & COATINGS TECHNOLOGY, 2005, 195 (2-3) :252-257